Kang Kyongok, Lettinga M P, Dogic Z, Dhont Jan K G
Institute für Festkörper Forschung (IFF), Weiche Materie, Forschungszentrum Jülich, D52425 Jülich, Germany.
Phys Rev E Stat Nonlin Soft Matter Phys. 2006 Aug;74(2 Pt 2):026307. doi: 10.1103/PhysRevE.74.026307. Epub 2006 Aug 28.
Vorticity banding under steady shear flow is observed in a suspension of semiflexible colloidal rods (fd virus particles) within a part of the paranematic-nematic biphasic region. Banding occurs uniformly throughout the cell gap within a shear-rate interval (.gamma-, .gamma+) , which depends on the fd concentration. For shear rates below the lower-border shear rate .gamma- only shear elongation of inhomogeneities, which are formed due to paranematic-nematic phase separation, is observed. Within a small region just above the upper-border shear rate .gamma+ , banding occurs heterogeneously. An essential difference in the kinetics of vorticity banding is observed, depending on the morphology of inhomogeneities formed during the initial stages of the paranematic-nematic phase separation. Particle tracking and polarization experiments indicate that the vorticity bands are in a weak rolling flow, superimposed on the applied shear flow. We propose a mechanism for the origin of the banding instability and the transient stability of the banded states. This mechanism is related to the normal stresses generated by inhomogeneities formed due to the underlying paranematic-nematic phase transition.
在近晶-向列双相区域的一部分内,在半柔性胶体棒(fd病毒颗粒)的悬浮液中观察到了稳定剪切流下的涡度带。在一个取决于fd浓度的剪切速率区间(γ-,γ+)内,带在整个细胞间隙中均匀出现。对于低于下边界剪切速率γ-的剪切速率,仅观察到由于近晶-向列相分离而形成的不均匀性的剪切伸长。在上边界剪切速率γ+上方的一个小区域内,带的出现是不均匀的。根据近晶-向列相分离初始阶段形成的不均匀性的形态,观察到涡度带动力学的一个本质区别。粒子跟踪和偏振实验表明,涡度带处于弱滚动流中,叠加在所施加的剪切流上。我们提出了一种关于带化不稳定性起源和带状状态瞬态稳定性的机制。该机制与由潜在的近晶-向列相变形成的不均匀性产生的法向应力有关。