烯丙醇有氧氧化反应中独特的金化学选择性
Unique gold chemoselectivity for the aerobic oxidation of allylic alcohols.
作者信息
Abad Alberto, Almela Carles, Corma Avelino, García Hermenegildo
机构信息
Instituto de Tecnología Química(CSIC-UPV), Universidad Politécnica de Valencia, Avda. de los Naranjos s/n, 46022 Valencia, Spain.
出版信息
Chem Commun (Camb). 2006 Aug 14(30):3178-80. doi: 10.1039/b606257a. Epub 2006 Jun 16.
DOI:10.1039/b606257a
PMID:17028735
Abstract
Gold nanoparticles supported on nanocrystalline ceria has been found to be more active and chemoselective than palladium and gold(core)-palladium(shell) nanoparticles for the aerobic oxidation of allylic alcohols.
摘要
已发现负载在纳米晶二氧化铈上的金纳米颗粒在烯丙醇的有氧氧化反应中比钯纳米颗粒以及金（核）-钯（壳）纳米颗粒更具活性和化学选择性。
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