Hill Nicholas J, Reeske Gregor, Moore Jennifer A, Cowley Alan H
Department of Chemistry and Biochemistry, University of Texas at Austin, Austin, Texas 78712, USA.
Dalton Trans. 2006 Oct 28(40):4838-44. doi: 10.1039/b609737e. Epub 2006 Aug 18.
The new Ar-BIAN complexes [(mes-BIAN)InCl(3)(THF)] (1), [(mes-BIAN)(2)Tl][PF(6)] (2), [(dipp-BIAN)SnCl(4)] (3), [(dipp-BIAN)SbCl(3)] (4), [(dipp-BIAN)BiCl(3)] (5) and [(mes-BIAN)BiCl(3)] (6) have been prepared by treatment of the neutral mes- and dipp-substituted BIAN ligands with the p-block reagents InCl(3), TlPF(6), SnCl(4), SbCl(3), and BiCl(3). The molecular structures of complexes 1-6 have been determined by single-crystal X-ray diffraction methods. However, only the atom connectivity was established for 5.
新型Ar-BIAN配合物[(mes-BIAN)InCl(3)(THF)] (1)、[(mes-BIAN)(2)Tl][PF(6)] (2)、[(dipp-BIAN)SnCl(4)] (3)、[(dipp-BIAN)SbCl(3)] (4)、[(dipp-BIAN)BiCl(3)] (5)和[(mes-BIAN)BiCl(3)] (6)是通过用p区试剂InCl(3)、TlPF(6)、SnCl(4)、SbCl(3)和BiCl(3)处理中性的间位和邻位取代的BIAN配体制备而成。配合物1 - 6的分子结构已通过单晶X射线衍射方法确定。然而，对于5仅确定了原子连接性。
