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阴离子型稀土硫氰酸盐配合物作为低熔点含金属离子液体的构建基块。

Anionic rare-earth thiocyanate complexes as building blocks for low-melting metal-containing ionic liquids.

作者信息

Nockemann Peter, Thijs Ben, Postelmans Niels, Van Hecke Kristof, Van Meervelt Luc, Binnemans Koen

机构信息

Department of Chemistry, Katholieke Universiteit Leuven, Celestijnenlaan 200F, B-3001 Leuven, Belgium.

出版信息

J Am Chem Soc. 2006 Oct 25;128(42):13658-9. doi: 10.1021/ja0640391.

DOI:10.1021/ja0640391
PMID:17044672
Abstract

The first examples of ionic liquids with rare-earth-containing anions are presented. These ionic liquids based on rare-earth thiocyanate complexes are liquid at room temperature, despite the multivalent character of the anionic building blocks.

摘要

首次展示了含有稀土阴离子的离子液体的实例。这些基于稀土硫氰酸盐配合物的离子液体在室温下呈液态，尽管阴离子结构单元具有多价特性。

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