Lv Lu, Wang Kean, Zhao X S
Department of Chemical & Biomolecular Engineering, National University of Singapore, 4 Engineering Drive 4, 117576 Singapore.
J Colloid Interface Sci. 2007 Jan 15;305(2):218-25. doi: 10.1016/j.jcis.2006.09.053. Epub 2006 Sep 26.
The breakthrough behavior of Pb2+ in an ETS-10 fixed bed was experimentally examined at various operating conditions. Results showed that the adsorption amount of Pb2+ ions per unit mass of ETS-10 particles in a column is about 1.68 mmol/g under the experimental conditions. This amount was not markedly affected by the operating conditions because of the rapid adsorption rate of Pb2+ ions on ETS-10. In the presence of competitive metal ions, the amount of Pb2+ adsorbed on ETS-10 was slightly reduced. An overshoot of the effluent concentrations of competitive metal ions Cu2+ and Cd2+ was observed in the adsorption systems of binary and ternary solutions. This is ascribed to the replacement of pre-adsorbed Cu2+ and Cd2+ ions by Pb2+ ions. The ETS-10 column broken up by Pb2+ ions can be regenerated by using an EDTA-Na2 solution and the regenerated column can be reused.
