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用仪器中子活化分析法测定气溶胶样品中的微量元素。

Determination of trace elements in aerosol samples by instrumental neutron activation analysis.

作者信息

Paiva R P, Munita C J, Cunha I I, Romano J, Alonso C D

机构信息

Instituto de Pesquisas Energéticas e Nucleares, IPEN-CNEN/SP, Radiochemistry Division, São Paulo, Brazil.

出版信息

Biol Trace Elem Res. 1990 Jul-Dec;26-27:231-42. doi: 10.1007/BF02992676.

Abstract

Two nuclear techniques, Energy-Dispersive X-Ray Fluorescence Analysis (EDXRF) and Instrumental Neutron Activation Analysis (INAA), were used to analyze aerosol samples collected in the city of São Paulo, Brazil. Na, Cl, Mn, V, Al, Sm, Mo, W, La, As, Br, Sb, K, Ba, Se, Th, Cr, Rb, Ca, Fe, Ce, and Sc were determined by INAA, and Al, Si, P, S, Cl, K, Ca, Ti, V, Cr, Mn, Fe, Ni, Cu, Zn, Ga, As, Se, Br, Rb, Sr, Hg, and Pb were determined by EDXRF. A preliminary identification of the main source of the atmospheric aerosol was performed based on enrichment factor and correlation coefficient calculations.

摘要

采用两种核技术,即能量色散X射线荧光分析(EDXRF)和仪器中子活化分析(INAA),对在巴西圣保罗市采集的气溶胶样品进行分析。通过仪器中子活化分析测定钠、氯、锰、钒、铝、钐、钼、钨、镧、砷、溴、锑、钾、钡、硒、钍、铬、铷、钙、铁、铈和钪,通过能量色散X射线荧光分析测定铝、硅、磷、硫、氯、钾、钙、钛、钒、铬、锰、铁、镍、铜、锌、镓、砷、硒、溴、铷、锶、汞和铅。基于富集因子和相关系数计算对大气气溶胶的主要来源进行了初步识别。

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