一种具有超分子螺旋结构的[60]富勒烯的旋光性液晶六加合物。
An optically-active liquid-crystalline hexa-adduct of [60]fullerene which displays supramolecular helical organization.
作者信息
Campidelli Stéphane, Brandmüller Torsten, Hirsch Andreas, Saez Isabel M, Goodby John W, Deschenaux Robert
机构信息
Institut de Chimie, Université de Neuchâtel, Avenue de Bellevaux 51, Case postale 158, 2009 Neuchâtel, Switzerland.
出版信息
Chem Commun (Camb). 2006 Nov 4(41):4282-4. doi: 10.1039/b610350b. Epub 2006 Sep 25.
DOI:10.1039/b610350b
PMID:17047841
Abstract
Polyaddition of mesogenic moieties to C60 were found to yield chiral supermolecular nanoparticles which exhibit iridescent helical chiral nematic phases.
摘要
研究发现，将介晶部分与C60进行聚加成反应可生成手性超分子纳米颗粒，这些颗粒呈现出彩虹色的螺旋手性向列相。
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