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某些阴离子对土壤中氨基酸在薄层色谱中迁移率的影响

Effect of some anions on the mobility of amino acids in soils by thin layer chromatography.

作者信息

Khan Samiullah, Moheman A

机构信息

Department of Applied Chemistry, ZH College of Engg & Tech, Aligarh Muslim University, India.

出版信息

J Environ Sci Eng. 2005 Oct;47(4):310-5.

Abstract

The mobility rate of some cyclic and aliphatic amino acids in terms of Rf values by using soil-thin layer chromatography shows the following order: glutamic acid > histidine > valine > leucine > serine > alanine. After conducting the studies to determine the effect of some anions, viz. MoO4(2-), B4O7(2-), C2O4(2-),CO3(2-), HCO3- and H2PO4- on the mobility of those amino acids, the mobility of the amino acids was found to increase with the increasing concentration of these anions up to a certain limit and thereafter the mobility rate declined except in case of glutamic acid which shows a fall in its movement throughout the entire range of their application in all cases. The results have been explained on the basis of a reaction mechanism involved in the interaction of these anionic species with soil colloids and amino acids in soil solution.

摘要

通过土壤薄层色谱法测定的某些环状和脂肪族氨基酸以比移值表示的迁移率显示出以下顺序

谷氨酸>组氨酸>缬氨酸>亮氨酸>丝氨酸>丙氨酸。在进行研究以确定某些阴离子,即钼酸根离子(MoO4(2-))、硼酸根离子(B4O7(2-))、草酸根离子(C2O4(2-))、碳酸根离子(CO3(2-))、碳酸氢根离子(HCO3-)和磷酸二氢根离子(H2PO4-)对这些氨基酸迁移率的影响后,发现氨基酸的迁移率随着这些阴离子浓度的增加而增加,直至达到一定限度,此后迁移率下降,但谷氨酸除外,在所有情况下,谷氨酸在其整个应用范围内的迁移率均下降。已根据这些阴离子物种与土壤胶体和土壤溶液中氨基酸相互作用所涉及的反应机制对结果进行了解释。

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