通过自组装制备的蜂窝状和针垫状聚合物薄膜的化学镀。

Electroless plating of honeycomb and pincushion polymer films prepared by self-organization.

作者信息

Yabu Hiroshi, Hirai Yuji, Shimomura Masatsugu

机构信息

Nanotechnology Research Center, Research Institute for Electronic Science, Hokkaido University, N21W10, Sapporo, 001-0021, Japan.

出版信息

Langmuir. 2006 Nov 7;22(23):9760-4. doi: 10.1021/la062228r.

DOI:10.1021/la062228r

PMID:17073508

Abstract

This report describes the fabrication and electroless plating of regular porous and pincushion-like polymer structures prepared by self-organization. Honeycomb-patterned films were prepared by simple casting of polymer solution under applied humid air and pincushion structures by peeling off the top layer of the former films. Silver-deposited honeycomb-patterned films and pincushion films were obtained by simple electroless plating of the respective original structures. XPS revealed Ag deposition on the honeycomb-patterned film. After thermal decomposition or solvent elution of the template polymer, unique metal mesoscopic structures were obtained.

摘要

本报告描述了通过自组装制备的规则多孔和针垫状聚合物结构的制造及化学镀。通过在施加潮湿空气的条件下简单浇铸聚合物溶液制备蜂窝状图案薄膜，并通过剥离前者薄膜的顶层制备针垫结构。通过对相应原始结构进行简单化学镀获得银沉积的蜂窝状图案薄膜和针垫薄膜。X射线光电子能谱（XPS）显示银沉积在蜂窝状图案薄膜上。在模板聚合物进行热分解或溶剂洗脱后，获得了独特的金属介观结构。