Benzo[a]acecorannulene: surprising formation of a new bowl-shaped aromatic hydrocarbon from an attempted synthesis of 1,2-diazadibenzo[d,m]corannulene.
作者信息
Tsefrikas Vikki M, Arns Steve, Merner Patrick M, Warford C Chad, Merner Bradley L, Scott Lawrence T, Bodwell Graham J
机构信息
Department of Chemistry, Memorial University of Newfoundland, St. John's, Newfoundland, Canada AlB 3X7.
出版信息
Org Lett. 2006 Nov 9;8(23):5195-8. doi: 10.1021/ol061554v.
PMID:17078676
Abstract
[Structure: see text] Flash vacuum pyrolysis of 7,10-bis(2-bromophenyl)acenaphtho[1,2-d]pyridazine (C26H14Br2N2) has resulted in a surprising transformation, including dinitrogen loss, to give benzo[a]acecorannulene, a novel C26H12 bowl-shaped fullerene fragment.
摘要
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