Tan Boon-Hooi, Yoshio Masafumi, Ichikawa Takahiro, Mukai Tomohiro, Ohno Hiroyuki, Kato Takashi
Department of Chemistry and Biotechnology, School of Engineering, The University of Tokyo, Hongo, Tokyo, 113-8656, Japan.
Chem Commun (Camb). 2006 Dec 7(45):4703-5. doi: 10.1039/b610903a. Epub 2006 Oct 4.
Hexagonal columnar liquid-crystalline phases are induced for a new fan-shaped spiropyran compound as the result of an acidichromism effect of spiro-merocyanine isomerisation through protonation upon incorporation of 4-methylbenzenesulfonic acid.
由于在加入4-甲基苯磺酸后通过质子化作用使螺-部花青异构化产生酸致变色效应,一种新型扇形螺吡喃化合物可诱导出六方柱状液晶相。