弹簧加载装置中的盘绕分子。
Coiled molecules in spring loaded devices.
作者信息
Ajami Dariush, Rebek Julius
机构信息
Department of Chemistry and The Skaggs Institute for Chemical Biology, The Scripps Research Institute, La Jolla, California 92037, USA.
出版信息
J Am Chem Soc. 2006 Nov 29;128(47):15038-9. doi: 10.1021/ja064233n.
PMID:17117825
Abstract
A cylindrical capsule containing a coiled alkane incorporates spacers. The alkane lengthens and gauche strain is relieved. The spacer can be removed to reset the system to the original state. The system represents a spring-loaded device that operates reversibly in response to acids and bases.
摘要
一个装有盘绕烷烃的圆柱形胶囊包含间隔物。烷烃伸长且扭转应变得到缓解。间隔物可以移除，以使系统重置到原始状态。该系统代表一种弹簧加载装置，可响应酸和碱进行可逆操作。
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