Fu P, Zhang W-D, Liu R H, Li T-Z, Shen Y-H, Li H-L, Zhang W, Chen H-S
Department of Phytochemistry, College of Pharmacy, Second Military Medical University, Shanghai, PR China.
Nat Prod Res. 2006 Nov;20(13):1237-40. doi: 10.1080/14786410600906095.
Two new xanthones, 1,6-dihydroxyisojacereubin-5-O-beta-D-glucoside (1) and 3,6,7-tri-hydroxy-1-methoxy-xanthone (2), were isolated from Hypericum japonicum. The structural elucidation of the isolated compounds were primarily based on HREIMS, EIMS, UV, IR, 1D-, and 2D-NMR analyses, including COSY, HMQC, HMBC, and NOESY correlations.
从地耳草中分离得到两个新的呫吨酮,1,6-二羟基异金丝桃素-5-O-β-D-葡萄糖苷(1)和3,6,7-三羟基-1-甲氧基呫吨酮(2)。分离得到化合物的结构解析主要基于高分辨电子轰击质谱(HREIMS)、电子轰击质谱(EIMS)、紫外光谱(UV)、红外光谱(IR)、一维和二维核磁共振(1D-和2D-NMR)分析,包括化学位移相关谱(COSY)、异核多量子相干谱(HMQC)、异核多键相关谱(HMBC)和核Overhauser效应谱(NOESY)相关。