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[Cu(HF₂)(pyz)₂]BF₄（pyz = 吡嗪）：一种由桥连的HF₂⁻和吡嗪配体组成的伪立方配位聚合物中的长程磁有序。

[Cu(HF2)(pyz)2]BF4 (pyz = pyrazine): long-range magnetic ordering in a pseudo-cubic coordination polymer comprised of bridging HF2- and pyrazine ligands.

作者信息

Manson Jamie L, Conner Marianne M, Schlueter John A, Lancaster Tom, Blundell Stephen J, Brooks Michael L, Pratt Francis L, Papageorgiou Thomas, Bianchi Andreas D, Wosnitza Jochen, Whangbo Myung-Hwan

机构信息

Department of Chemistry and Biochemistry, Eastern Washington University, Cheney, WA 99004, USA.

出版信息

Chem Commun (Camb). 2006 Dec 21(47):4894-6. doi: 10.1039/b608791d. Epub 2006 Aug 22.

DOI:10.1039/b608791d
PMID:17136238
Abstract

[Cu(HF2)(pyz)2]BF4 consists of rare mu(1,3) bridging HF2- anions and micro-pyrazine ligands leading to a 3D pseudo-cubic framework that antiferromagnetically orders below 1.54(1) K.

摘要

四氟硼酸二吡嗪铜（II）由罕见的μ(1,3)桥连二氟氢根阴离子和微吡嗪配体组成，形成三维伪立方框架，在1.54(1)K以下呈现反铁磁有序。

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