通过铃木交叉偶联反应制备碳硼烷官能化的吡咯和卟啉。
Carborane functionalized pyrroles and porphyrins via the Suzuki cross-coupling reaction.
作者信息
Hao Erhong, Fronczek Frank R, Vicente M Graça H
机构信息
Department of Chemistry, Louisiana State University, Baton Rouge, LA 70803, USA.
出版信息
Chem Commun (Camb). 2006 Dec 21(47):4900-2. doi: 10.1039/b611571c. Epub 2006 Oct 5.
DOI:10.1039/b611571c
PMID:17136240
Abstract
A new route to carboranylated pyrroles and porphyrins is reported which involves the Suzuki coupling of readily available bromo- and boronic acid-pyrroles and bromoporphyrins with functionalized carboranes; the X-ray structures of two targeted products are presented and discussed.
摘要
报道了一种合成碳硼烷基化吡咯和卟啉的新方法，该方法涉及将易于获得的溴代和硼酸基吡咯以及溴代卟啉与功能化碳硼烷进行铃木偶联反应；给出并讨论了两种目标产物的X射线结构。
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