Green Shaun P, Jones Cameron, Stasch Andreas
Center for Fundamental and Applied Main Group Chemistry, School of Chemistry, Main Building, Cardiff University, Cardiff CF10 3AT, UK.
Inorg Chem. 2007 Jan 8;46(1):11-3. doi: 10.1021/ic062057d.
A series of complexes between recently developed four-membered group 13 metal(I) heterocycles and group 10 metal(0) fragments have been prepared and structurally characterized. One prepared complex, [Pt{Ga[N(Ar)]2CNCy2}3] (Ar = C6H3Pri2-2,6; Cy = cyclohexyl), possesses the shortest Pt-Ga bonds yet reported, the covalent components of which are suggested by theoretical studies to have significant pi character.
一系列由最近开发的四元13族金属（I）杂环与10族金属（0）片段形成的配合物已被制备并进行了结构表征。制备的一种配合物[Pt{Ga[N(Ar)]2CNCy2}3]（Ar = C6H3Pri2-2,6；Cy = 环己基）具有迄今报道的最短Pt-Ga键，理论研究表明其共价成分具有显著的π特性。
