Nayak Nimai C, Shin Kwanwoo
Department of Materials Science and Engineering, Gwangju Institute Science and Technology, Gwangju, 500712, Korea.
J Nanosci Nanotechnol. 2006 Nov;6(11):3512-6.
Here we described the two synthesis methods of L-phenylalanine (L-phe) coated gold nanoparticles through a reduction of aqueous chloroaurate ions directly by L-phe, and also the borohydride reduction of chloroauric acid followed by capping with L-phe molecules. Phenylalanine reduced gold nanoparticles and the phenylalanine capped gold nanoparticles were evaluated by transmission electron microscope and UV-vis spectroscopy, and then their thermal stabilities were compared. We found that the phenylalanine reduced gold nanoparticles were unstable and form linearly arranged aggregates on aging, while as the phenylalanine capped gold nanoparticles were stable for months in ambient condition.
在此,我们描述了通过L-苯丙氨酸(L-phe)直接还原氯金酸根离子水溶液以及硼氢化钠还原氯金酸后用L-phe分子封端这两种合成L-苯丙氨酸包覆金纳米颗粒的方法。通过透射电子显微镜和紫外可见光谱对苯丙氨酸还原的金纳米颗粒和苯丙氨酸封端的金纳米颗粒进行了评估,然后比较了它们的热稳定性。我们发现,苯丙氨酸还原的金纳米颗粒不稳定,老化时会形成线性排列的聚集体,而苯丙氨酸封端的金纳米颗粒在环境条件下可稳定存在数月。