一个（H₃O₂）⁻单元被包封在杯[6]芳烃的芳香核中，该芳香核在小边缘和大边缘处由两个Zn（II）离子封闭。
Encapsulation of a (H3O2)- unit in the aromatic core of a calix[6]arene closed by two Zn(II) ions at the small and large rims.
作者信息
Coquière David, Marrot Jérôme, Reinaud Olivia
机构信息
Laboratoire de Chimie et Biochimie Pharmacologiques et Toxicologiques, UMR CNRS 8601, Université René Descartes, 45 rue des Saints-Pères, 75270 Paris Cedex 06, France.
出版信息
Chem Commun (Camb). 2006 Oct 1(37):3924-6. doi: 10.1039/b608203c. Epub 2006 Aug 4.
DOI:10.1039/b608203c
PMID:17268672
Abstract
The coordination of a first Zn(II) ion to a calix[6]arene presenting three imidazolyl arms at the small rim and three aniline moieties at the large rim allows the binding of a second Zn(II) ion while hosting a (H3O2)- unit in the aromatic cavity.
摘要
一个锌（II）离子与一个在小环带有三个咪唑基臂且在大环带有三个苯胺部分的杯[6]芳烃配位，使得在芳香腔容纳一个（H₃O₂）⁺单元的同时能够结合第二个锌（II）离子。
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