超分子聚合物的物理有机化学
Physical organic chemistry of supramolecular polymers.
作者信息
Serpe Michael J, Craig Stephen L
机构信息
Department of Chemistry and Center for Biologically Inspired Materials and Material Systems, Duke University, Durham, North Carolina 27708-0346, USA.
出版信息
Langmuir. 2007 Feb 13;23(4):1626-34. doi: 10.1021/la0621416.
Abstract
Unlike the case of traditional covalent polymers, the entanglements that determine properties of supramolecular polymers are defined by very specific, intermolecular interactions. Recent work using modular molecular platforms to probe the mechanisms underlying mechanical response of supramolecular polymers is reviewed. The contributions of supramolecular kinetics, thermodynamics, and conformational flexibility to supramolecular polymer properties in solutions of discrete polymers, in networks, and at interfaces, are described. Molecule-to-material relationships are established through methods reminiscent of classic physical organic chemistry.
摘要
与传统共价聚合物的情况不同，决定超分子聚合物性质的缠结是由非常特殊的分子间相互作用定义的。本文综述了利用模块化分子平台探究超分子聚合物机械响应潜在机制的最新研究工作。描述了超分子动力学、热力学和构象灵活性对离散聚合物溶液、网络及界面中超分子聚合物性质的贡献。通过类似于经典物理有机化学的方法建立了分子与材料之间的关系。
相似文献
1
Physical organic chemistry of supramolecular polymers.
Langmuir. 2007 Feb 13;23(4):1626-34. doi: 10.1021/la0621416.
2
Toward self-organization and complex matter.
Science. 2002 Mar 29;295(5564):2400-3. doi: 10.1126/science.1071063.
3
Constructing monocrystalline covalent organic networks by polymerization.
Nat Chem. 2013 Oct;5(10):830-4. doi: 10.1038/nchem.1730. Epub 2013 Aug 25.
4
Macromolecular crowding: chemistry and physics meet biology (Ascona, Switzerland, 10-14 June 2012).
Phys Biol. 2013 Aug;10(4):040301. doi: 10.1088/1478-3975/10/4/040301. Epub 2013 Aug 2.
5
Conformational aspects of polypeptide structure. XXII. Aromatic side-chain effects from poly-L-p-aminophenylalanine and derivatives.
Biochemistry. 1967 May;6(5):1533-40. doi: 10.1021/bi00857a040.
6
Supramolecular polymers generated from heterocomplementary monomers linked through multiple hydrogen-bonding arrays--formation, characterization, and properties.
Chemistry. 2002 Mar 1;8(5):1227-44. doi: 10.1002/1521-3765(20020301)8:5<1227::aid-chem1227>3.0.co;2-0.
7
Synthesis beyond the molecule.
Science. 2002 Mar 29;295(5564):2403-7. doi: 10.1126/science.1069197.
8
Supramolecular Chemistry in Microflow Fields: Toward a New Material World of Precise Kinetic Control.
Chem Asian J. 2015 Dec;10(12):2574-88. doi: 10.1002/asia.201500555. Epub 2015 Sep 15.
9
Olefin metathesis and quadruple hydrogen bonding: a powerful combination in multistep supramolecular synthesis.
Proc Natl Acad Sci U S A. 2006 Aug 8;103(32):11850-5. doi: 10.1073/pnas.0602413103. Epub 2006 Jul 28.
10
Polymer supports in organic catalysis and synthesis.
Curr Opin Drug Discov Devel. 2001 Nov;4(6):736-44.
引用本文的文献
1
Structure-Reactivity-Property Relationships in Covalent Adaptable Networks.
J Am Chem Soc. 2022 Dec 14;144(49):22358-22377. doi: 10.1021/jacs.2c08104. Epub 2022 Nov 29.
2
Moving while you're stuck: a macroscopic demonstration of an active system inspired by binding-mediated transport in biology.
Soft Matter. 2021 Mar 18;17(10):2957-2962. doi: 10.1039/d0sm01808b.
3
Design of materials with supramolecular polymers.
Prog Polym Sci. 2020 Dec;111:101310. doi: 10.1016/j.progpolymsci.2020.101310. Epub 2020 Oct 15.
4
pH-Responsive Polyketone/5,10,15,20-Tetrakis-(Sulfonatophenyl)Porphyrin Supramolecular Submicron Colloidal Structures.
Polymers (Basel). 2020 Sep 3;12(9):2017. doi: 10.3390/polym12092017.
5
A Critical Approach to Polymer Dynamics in Supramolecular Polymers.
Macromolecules. 2019 Dec 24;52(24):9427-9444. doi: 10.1021/acs.macromol.9b02085. Epub 2019 Dec 16.
6
The Chain Distribution Tensor: Linking Nonlinear Rheology and Chain Anisotropy in Transient Polymers.
Polymers (Basel). 2018 Aug 1;10(8):848. doi: 10.3390/polym10080848.
7
Reversibly tuning hydrogel stiffness through photocontrolled dynamic covalent crosslinks.
Chem Sci. 2018 Jun 19;9(27):5987-5993. doi: 10.1039/c8sc02093k. eCollection 2018 Jul 21.
8
Direct correlation of single-molecule properties with bulk mechanical performance for the biomimetic design of polymers.
Nat Mater. 2014 Nov;13(11):1055-62. doi: 10.1038/nmat4090. Epub 2014 Sep 28.
9
From Brittle to Pliant Viscoelastic Materials with Solid State Linear Polyphosphonium - Carboxylate Assemblies.
Macromolecules. 2012 Mar 13;45(5):2509-2513. doi: 10.1021/ma3002092.
10
Single-Molecule Force Spectroscopy of DNA-Based Reversible Polymer Bridges: Surface Robustness and Homogeneity.
Colloids Surf A Physicochem Eng Asp. 2009 Aug 20;346(1-3):20-27. doi: 10.1016/j.colsurfa.2009.05.019.
本文引用的文献
1
Polymerization of Ureidopyrimidinone-Functionalized Olefins by Using Late-Transition Metal Ziegler-Natta Catalysts: Synthesis of Thermoplastic Elastomeric Polyolefins.
Angew Chem Int Ed Engl. 2001 Jun 1;40(11):2153-2156. doi: 10.1002/1521-3773(20010601)40:11<2153::AID-ANIE2153>3.0.CO;2-W.
2
Platinum Group Organometallics Based on "Pincer" Complexes: Sensors, Switches, and Catalysts.
Angew Chem Int Ed Engl. 2001 Oct 15;40(20):3750-3781. doi: 10.1002/1521-3773(20011015)40:20<3750::AID-ANIE3750>3.0.CO;2-6.
3
Specific Hydrogen-Bond-Mediated Recognition and Modification of Surfaces Using Complementary Functionalized Polymers.
Langmuir. 2003 Aug 19;19(17):7089-7093. doi: 10.1021/la034809b.
4
Reversibly cross-linked surface-grafted polymer brushes.
Angew Chem Int Ed Engl. 2006 Nov 27;45(46):7812-4. doi: 10.1002/anie.200602508.
5
Quantification of ultrasound-induced chain scission in PdII-phosphine coordination polymers.
Chemistry. 2006 Jun 14;12(18):4928-34. doi: 10.1002/chem.200600120.
6
Single-molecule force spectroscopy of bimolecular reactions: system homology in the mechanical activation of ligand substitution reactions.
J Am Chem Soc. 2006 Mar 29;128(12):3886-7. doi: 10.1021/ja058516b.
7
Self-assembly with block copolymers through metal coordination of SCS-Pd(II) pincer complexes and pseudorotaxane formation.
Chemistry. 2006 May 3;12(14):3789-97. doi: 10.1002/chem.200501028.
8
Utilization of a combination of weak hydrogen-bonding interactions and phase segregation to yield highly thermosensitive supramolecular polymers.
J Am Chem Soc. 2005 Dec 28;127(51):18202-11. doi: 10.1021/ja055245w.
9
Thermally reversible formation of microspheres through non-covalent polymer cross-linking.
J Am Chem Soc. 2003 Sep 17;125(37):11249-52. doi: 10.1021/ja034868b.
10
Small-molecule dynamics and mechanisms underlying the macroscopic mechanical properties of coordinatively cross-linked polymer networks.
J Am Chem Soc. 2005 Oct 19;127(41):14488-96. doi: 10.1021/ja054298a.
Zotero 插件