Faget L, Lamarque-Forget S, Martinot-Lagarde Ph, Auroy P, Dozov I
Nemoptic, Parc du Mérantais, 1 rue Guynemer, F-78114 Magny-les-Hameaux, France.
Phys Rev E Stat Nonlin Soft Matter Phys. 2006 Nov;74(5 Pt 1):050701. doi: 10.1103/PhysRevE.74.050701. Epub 2006 Nov 30.
Recent works reported planar and conical azimuthally degenerated nematic anchorings. Here we predict an additional "anticonical" degenerated anchoring. Its energy presents two minima, parallel and perpendicular to the substrate plane, separated by a conical energy barrier. We realize this bistable anchoring on a grafted polymer brush and we observe temperature-driven transitions between the conical, planar, and anticonical degenerated anchorings. Under electric field we break the anticonical anchoring and switch between its bistable states.
近期的研究报道了平面和圆锥方位简并向列相锚定。在此,我们预测了一种额外的“反圆锥”简并锚定。其能量呈现出两个最小值,分别平行和垂直于衬底平面,由一个圆锥能量势垒隔开。我们在接枝聚合物刷上实现了这种双稳态锚定,并观察到在圆锥、平面和反圆锥简并锚定之间的温度驱动转变。在电场作用下,我们打破了反圆锥锚定并在其双稳态之间切换。