Ntai Ioanna, Phelan Vanessa V, Bachmann Brian O
Vanderbilt University Chemistry Department, Nashville, TN, USA.
Chem Commun (Camb). 2006 Nov 21(43):4518-20. doi: 10.1039/b611768f.
Precursors and advanced intermediates for phosphonopeptide K-26 biosynthesis were synthesized and incorporation studies in Astrosporangium hypotensionis suggest a new mechanism of C-P bond formation in aromatic phosphonates.
合成了磷肽K-26生物合成的前体和高级中间体,在低血压星孢菌中的掺入研究表明了芳香族膦酸酯中C-P键形成的新机制。