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从生物矿化到燃料电池:用于燃料电池电极催化剂的铂和钯纳米晶体的生物制造

From bio-mineralisation to fuel cells: biomanufacture of Pt and Pd nanocrystals for fuel cell electrode catalyst.

作者信息

Yong P, Paterson-Beedle M, Mikheenko I P, Macaskie L E

机构信息

Unit of Functional Bionanomaterials, School of Biosciences, University of Birmingham, Edgbaston, Birmingham, UK.

出版信息

Biotechnol Lett. 2007 Apr;29(4):539-44. doi: 10.1007/s10529-006-9283-4. Epub 2007 Feb 13.

Abstract

Biosynthesis of nano-scale platinum and palladium was achieved via enzymatically-mediated deposition of metal ions from solution. The bio-accumulated Pt(0) and Pd(0) crystals were dried, applied onto carbon paper and tested as anodes in a polymer electrolyte membrane (PEM) fuel cell for power production. Up to 100% and 81% of the maximum power generation was achieved by the bio-Pt and bio-Pd catalysts, respectively, compared to commercial fuel cell grade Pt catalyst. Hence, biomineralisation could pave the way for economical production of fuel cell catalysts since previous studies have shown that precious metals can be biorecovered from wastes into catalytically active bionanomaterials.

摘要

通过酶介导从溶液中沉积金属离子实现了纳米级铂和钯的生物合成。将生物积累的Pt(0)和Pd(0)晶体干燥后,涂覆在碳纸上,并作为阳极在聚合物电解质膜(PEM)燃料电池中进行发电测试。与商业燃料电池级Pt催化剂相比,生物Pt和生物Pd催化剂分别实现了高达100%和81%的最大功率发电。因此,生物矿化可为燃料电池催化剂的经济生产铺平道路,因为先前的研究表明,贵金属可从废物中生物回收为具有催化活性的生物纳米材料。

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