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某些选定橡胶衍生物的傅里叶变换红外光谱及机械强度分析

FTIR spectra and mechanical strength analysis of some selected rubber derivatives.

作者信息

Gunasekaran S, Natarajan R K, Kala A

机构信息

PG & Research Department of Physics, Pachaiyappa's College, Chennai 600 030, India.

出版信息

Spectrochim Acta A Mol Biomol Spectrosc. 2007 Oct;68(2):323-30. doi: 10.1016/j.saa.2006.11.039. Epub 2006 Dec 8.

Abstract

Rubber materials have wide range of commercial applications such as, infant diapers, famine hygiene products, drug delivery devices and incontinency products such as rubber tubes, tyres, etc. In the present work, studies on mechanical properties of some selected rubber materials viz., natural rubber (NR), styrene butadiene rubber (SBR), nitrile butadiene rubber (NBR) and ethylene propylene diene monomer (EPDM) have been carried out in three states viz., raw, vulcanized and reinforced. To enhance the quality of rubber elastomers, an attempt is made to prepare new elastomers called polyblends. In the present study an attempt is made to blend NR with NBR and with EPDM. We here report, a novel approach for the evaluation of various physico-mechanical properties such as mechanical strength, tensile strength, elongation and hardness. The method is simple, direct and fast and involves infrared spectral measurements for the evaluation of these properties. With the applications of modern infrared spectroscopy, the mechanical strength of these rubber materials have been analyzed by calculating the internal standards among the methyl and methylene group vibrational frequencies obtained from FTIR spectroscopy. Also the tensile strength measurements carried out by universal testing machine. The results pertaining physico-mechanical properties of the rubber derivatives undertaken in the present study obtained by IR-based method are in good agreement with data resulted from the standard methods.

摘要

橡胶材料有广泛的商业应用,如婴儿尿布、女性卫生用品、药物输送装置以及诸如橡胶管、轮胎等失禁用品。在本研究中,对一些选定的橡胶材料,即天然橡胶(NR)、丁苯橡胶(SBR)、丁腈橡胶(NBR)和三元乙丙橡胶(EPDM)在三种状态下,即未加工、硫化和增强状态下的力学性能进行了研究。为提高橡胶弹性体的质量,尝试制备称为共混物的新型弹性体。在本研究中,尝试将天然橡胶与丁腈橡胶以及与三元乙丙橡胶进行共混。我们在此报告一种评估各种物理力学性能(如机械强度、拉伸强度、伸长率和硬度)的新方法。该方法简单、直接且快速,涉及通过红外光谱测量来评估这些性能。通过应用现代红外光谱,通过计算从傅里叶变换红外光谱(FTIR)获得的甲基和亚甲基基团振动频率之间的内标,对这些橡胶材料的机械强度进行了分析。拉伸强度测量由万能试验机进行。本研究中通过基于红外的方法获得的橡胶衍生物的物理力学性能结果与标准方法得到的数据高度一致。

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