首例基于吡唑的钯（II）远程N-杂环卡宾配合物的制备与表征
Preparation and characterization of the first pyrazole-based remote N-heterocyclic carbene complexes of palladium(II).
作者信息
Han Yuan, Huynh Han Vinh
机构信息
Department of Chemistry, National University of Singapore, 3 Science Drive 3, 117543, Singapore, Singapore.
出版信息
Chem Commun (Camb). 2007 Mar 14(10):1089-91. doi: 10.1039/b615441g. Epub 2007 Jan 5.
DOI:10.1039/b615441g
PMID:17325815
Abstract
The first pyrazolin-4-ylidene complexes of palladium(II) have been synthesized by oxidative addition of 4-iodopyrazolium salts to Pd(2)(dba)3/PPh(3) and were fully characterized by multinuclear NMR spectroscopies, ESI mass spectrometry and X-ray diffraction studies.
摘要
通过将4-碘代吡唑盐氧化加成到Pd₂(dba)₃/PPh₃上，首次合成了钯(II)的吡唑啉-4-亚基配合物，并通过多核核磁共振光谱、电喷雾电离质谱和X射线衍射研究对其进行了全面表征。
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