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[微波强化染料从水中对表面活性剂与膨润土混合物的综合吸附作用机制及影响]

[Mechanism and impact for microwave-enhanced integrative sorption of dye to mixture of surfactant and bentonite from water].

作者信息

Li Ji-Wu, Zhu Li-Zhong, Cai Wei-Jian

机构信息

Department of Environmental Science, Zhejiang University, Hangzhou 310028, China.

出版信息

Huan Jing Ke Xue. 2006 Nov;27(11):2212-6.

Abstract

Microwave-enhanced integrative sorption (MEIS) of dye to mixture of surfactant and bentonite was put forward. The order of factor for integrative method was obtained by the orthogonal experiment. The optimal conditions, properties, kinetics and mechanisms for microwave-enhanced integrative sorption of Neutral Red S-BR to bentonite from water were investigated. Comparative study on decolorization rates of Neutral Red S-BR by other sorption method and MEIS from water were conducted. It is concluded that the order of factor for integrative method is amount of surfactant, bentonite and microwave time. The optimal condition for MEIS is that the ratio of amount of bentonite and water is equal to 1/1 000, the concentration of cetylpyridinium chloride (CPC) is 120 mg/L (equivalent to 28% cation exchange capacity of bentonite) and microwave time is 60s. Comparative with organobentonite, the decolorization rates of Neutral Red S-BR to bentonite are greatly increased by MEIS at higher concentration of dye, amount of surfactant is greatly decreased, and the saturated sorption capacity and the reactive rate of sorption of dye to bentonite are greatly increased by microwave.

摘要

提出了微波强化染料对表面活性剂与膨润土混合物的吸附(MEIS)方法。通过正交实验得出了该综合方法的因素顺序。研究了从水中微波强化中性红S - BR对膨润土的吸附的最佳条件、性能、动力学及机理。对其他吸附方法和MEIS从水中对中性红S - BR的脱色率进行了对比研究。结果表明,综合方法的因素顺序为表面活性剂用量、膨润土用量和微波时间。MEIS的最佳条件为:膨润土与水的用量比为1/1000,十六烷基吡啶氯化物(CPC)浓度为120mg/L(相当于膨润土阳离子交换容量的28%),微波时间为60s。与有机膨润土相比,在较高染料浓度下,MEIS大大提高了中性红S - BR对膨润土的脱色率,大大降低了表面活性剂用量,且微波大大提高了染料对膨润土的饱和吸附容量和吸附反应速率。

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