水合双（3-甲氧基-2-吡啶酮基）（2,2':6',2''-三联吡啶）钌（II）-乙腈-水（1/1/1）
Aquabis(3-methoxy-2-pyridonato)(2,2':6',2''-terpyridine)ruthenium(II)-acetonitrile-water (1/1/1).
作者信息
Kelson Eric P, Dean Norman S, Algarín Edgar
机构信息
Department of Chemistry and Biochemistry, California State University Northridge, 18111 Nordhoff Street, Northridge, CA 91330-8262, USA.
出版信息
Acta Crystallogr C. 2007 Mar;63(Pt 3):m108-10. doi: 10.1107/S0108270107004246. Epub 2007 Feb 17.
The title compound, [Ru(C(6)H(6)NO(2))(2)(C(15)H(11)N(3))(H(2)O)] x CH(3)CNx H(2)O, is a transfer hydrogenation catalyst supported by nitrogen-donor ligands. This octahedral Ru(II) complex features rare monodentate coordination of 3-methoxy-2-pyridonate ligands and interligand S(6)S(6) hydrogen bonding. Comparison of the title complex with a structural analog with unsubstituted 2-pyridonate ligands reveals subtle differences in the orientation of the ligand planes.
标题化合物[Ru(C₆H₆NO₂)₂(C₁₅H₁₁N₃)(H₂O)]·CH₃CN·H₂O是一种由含氮配体支撑的转移氢化催化剂。这种八面体Ru(II)配合物具有罕见的3-甲氧基-2-吡啶酮配体单齿配位和配体间S(6)S(6)氢键。将标题配合物与具有未取代2-吡啶酮配体的结构类似物进行比较，揭示了配体平面取向的细微差异。
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