Villanova Daniela L, Bergmann Carlos P
Laboratório de Materiais Cerâmicos, DEMAT, Escola de Engenharia, UFRGS, Porto Alegre/RS, Brazil.
Waste Manag Res. 2007 Feb;25(1):77-82. doi: 10.1177/0734242X07069764.
The aim of this study was to investigate the sinterability to improve the technical properties of ceramic bodies made from coal bottom ash and soda-lime glass cullet. Different mixtures of bottom ash and glass cullet were formulated. The amount of bottom ash was 100, 70, 50 and 30 wt.%. The particle size distribution was the same for all formulations. The mixture containing 50 wt.% bottom ash also had its particle size distribution changed. Samples were formed by dry pressing and then fired at 950, 1050 and 1150 degrees C. Samples were evaluated for linear shrinkage, water absorption, flexural mechanical resistance, scanning electronic microscopy, pyroplastic deformation and thermodilatometric analysis. The higher firing temperature led to a decrease in water absorption and increased linear shrinkage, mechanical resistance and pyroplastic deformation. This effect was also observed for addition of glass up to 50 wt.%. The effect of smaller particles of bottom ash was more significant for linear shrinkage and mechanical resistance of ceramic bodies fired at 1150 degrees C. The use of a finer powder contributed to increase these properties. The influence of finer particles on water absorption and mechanical resistance of ceramic bodies fired at 950 and 1050 degrees C was not significant.
本研究的目的是研究烧结性,以改善由煤灰底灰和钠钙玻璃碎料制成的陶瓷体的技术性能。配制了不同比例的底灰和玻璃碎料混合物。底灰的含量分别为100%、70%、50%和30%(重量)。所有配方的粒度分布相同。含50%(重量)底灰的混合物其粒度分布也有所改变。通过干压成型样品,然后在950℃、1050℃和1150℃下烧制。对样品进行线性收缩、吸水率、抗弯机械强度、扫描电子显微镜、热塑性变形和热膨胀分析评估。较高的烧制温度导致吸水率降低,线性收缩、机械强度和热塑性变形增加。对于添加量高达50%(重量)的玻璃,也观察到了这种效果。对于在1150℃烧制的陶瓷体,底灰较小颗粒对线性收缩和机械强度的影响更为显著。使用更细的粉末有助于提高这些性能。细颗粒对在950℃和1050℃烧制的陶瓷体的吸水率和机械强度的影响不显著。