Dohi Toshifumi, Maruyama Akinobu, Minamitsuji Yutaka, Takenaga Naoko, Kita Yasuyuki
Graduate School of Pharmaceutical Sciences, Osaka University, 1-6 Yamada-oka, Suita, Osaka, 565-0871, Japan.
Chem Commun (Camb). 2007 Mar 28(12):1224-6. doi: 10.1039/b616510a. Epub 2006 Dec 22.
A protic solvent, 2,2,2-trifluoroethanol (CF(3)CH(2)OH), was successfully introduced into hypervalent iodine(III)-involved catalytic cycles as an effective solvent, and the first iodoarene-catalyzed intramolecular carbon-nitrogen bond forming reaction was achieved under strong acid-free and mild conditions.
一种质子性溶剂，2,2,2-三氟乙醇（CF(3)CH(2)OH），作为一种有效的溶剂成功引入到高价碘（III）参与的催化循环中，并且在无强酸和温和条件下实现了首例碘代芳烃催化的分子内碳-氮键形成反应。
