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通过相干X射线衍射重新审视SrTiO₃的位移转变。

SrTiO3 displacive transition revisited via coherent X-ray diffraction.

作者信息

Ravy S, Le Bolloc'h D, Currat R, Fluerasu A, Mocuta C, Dkhil B

机构信息

Synchrotron SOLEIL, L'Orme des merisiers, Saint-Aubin BP 48, 91192 Gif-sur-Yvette cedex, France.

出版信息

Phys Rev Lett. 2007 Mar 9;98(10):105501. doi: 10.1103/PhysRevLett.98.105501. Epub 2007 Mar 5.

Abstract

We present a coherent x-ray diffraction study of the antiferrodistortive displacive transition of SrTiO3, a prototypical example of a phase transition for which the critical fluctuations exhibit two length scales and two time scales. From the microbeam x-ray coherent diffraction patterns, we show that the broad (short-length scale) and the narrow (long-length scale) components can be spatially disentangled, due to 100-microm-scale spatial variations of the latter. Moreover, both components exhibit a speckle pattern, which is static on a approximately 10 mn time scale. This gives evidence that the narrow component corresponds to static ordered domains. We interpret the speckles in the broad component as due to a very slow dynamical process, corresponding to the well-known central peak seen in inelastic neutron scattering.

摘要

我们展示了对SrTiO₃反铁电畸变位移相变的相干X射线衍射研究,SrTiO₃是一种相变的典型例子,其临界涨落表现出两个长度尺度和两个时间尺度。从微束X射线相干衍射图案中,我们表明,由于后者存在100微米尺度的空间变化,宽(短长度尺度)和窄(长长度尺度)分量在空间上可以解缠。此外,两个分量都呈现出散斑图案,在大约10毫秒的时间尺度上是静态的。这证明窄分量对应于静态有序畴。我们将宽分量中的散斑解释为由于一个非常缓慢的动力学过程,这与非弹性中子散射中著名的中心峰相对应。

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