舞毒蛾信息素 disparlure 两种对映体的对映选择性合成。
Enantiodivergent synthesis of both enantiomers of gypsy moth pheromone disparlure.
作者信息
Prasad Kavirayani R, Anbarasan Pazhamalai
机构信息
Department of Organic Chemistry, Indian Institute of Science, Bangalore 560012, India.
出版信息
J Org Chem. 2007 Apr 13;72(8):3155-7. doi: 10.1021/jo070060o. Epub 2007 Mar 17.
PMID:17367199
Abstract
Enantiodivergent synthesis of both (-)- and (+)-disparlure, a bioactive pheromone, possessing a cis-epoxide has been accomplished. The key step involves the cross metathesis of a chiral homoallylic alcohol derived from l-(+)-tartaric acid.
摘要
具有顺式环氧化物的生物活性信息素（-）-和（+）-舞毒蛾性诱剂的对映发散合成已经完成。关键步骤涉及由L-（+）-酒石酸衍生的手性高烯丙醇的交叉复分解反应。
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