Fernandez Eduardo J, Laguna Antonio, López-de-Luzuriaga José M, Monge Miguel, Montiel Manuel, Olmos M Elena
Grupo de Síntesis Química de La Rioja, Departamento de Química, Universidad de La Rioja, UA-CSIC, Complejo Científico-Tecnológico, 26004 Logroño, Spain.
Inorg Chem. 2007 Apr 16;46(8):2953-5. doi: 10.1021/ic062127g. Epub 2007 Mar 21.
The dinuclear complex [[Tl(eta6-toluene)][Au(C6Cl5)2]] (1) displays very intense blue phosphorescence and a rigidochromic behavior in the solid state. The photophysical measurements in a glassy solution display an oligomerization process via metal-metal interactions. Density functional theory calculations show a distortion of the aurate-thallium T shape in the lowest triplet excited state, leading to a triplet metal-to-metal charge-transfer state.
双核配合物[[Tl(η6-甲苯)][Au(C6Cl5)2]] (1)在固态下呈现出非常强烈的蓝色磷光和刚性变色行为。在玻璃态溶液中的光物理测量显示通过金属-金属相互作用的低聚过程。密度泛函理论计算表明，在最低三重激发态下金铊T形发生畸变，导致三重态金属-金属电荷转移态。
