195铂核磁共振——理论与应用。
195Pt NMR--theory and application.
作者信息
Still Brett M, Kumar P G Anil, Aldrich-Wright Janice R, Price William S
机构信息
Nanoscale Organisation and Dynamics Group, College of Health and Science, University of Western Sydney, Penrith South DC, NSW 1797, Australia.
出版信息
Chem Soc Rev. 2007 Apr;36(4):665-86. doi: 10.1039/b606190g. Epub 2006 Nov 17.
This critical review highlights the progress in (195)Pt NMR over the last 25 years. In particular, some of the recent applications of (195)Pt NMR in catalytic and mechanistic studies, intermetallics and drug binding studies are discussed. (195)Pt NMR chemical shifts obtained from both theoretical studies and experiments are presented for Pt(0), Pt(II), Pt(III) and Pt(IV) complexes. (195)Pt coupling with various nuclei (viz. coupling constants) have also been collected in addition to data on (195)Pt relaxation. The latest developments in the theoretical knowledge and experimental advances have made (195)Pt NMR into a rich source of information in many fields. (164 references.).
这篇综述重点介绍了过去25年中¹⁹⁵Pt核磁共振（NMR）的进展。特别讨论了¹⁹⁵Pt NMR在催化和机理研究、金属间化合物及药物结合研究中的一些最新应用。文中给出了从理论研究和实验中获得的Pt(0)、Pt(II)、Pt(III)和Pt(IV)配合物的¹⁹⁵Pt NMR化学位移。除了¹⁹⁵Pt弛豫数据外，还收集了¹⁹⁵Pt与各种原子核的耦合（即耦合常数）。理论知识和实验进展的最新成果使¹⁹⁵Pt NMR成为许多领域丰富的信息来源。（参考文献164篇）
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