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不同极性各向同性介晶液体基本热力学量的电场诱导增量的预向列相行为

Prenematic behavior of the electric-field-induced increment of the basic thermodynamic quantities of isotropic mesogenic liquids of different polarity.

作者信息

Jadzyn Jan, Czechowski Grzegorz

机构信息

Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179 Poznań, Poland.

出版信息

J Phys Chem B. 2007 Apr 12;111(14):3727-9. doi: 10.1021/jp070569n. Epub 2007 Mar 20.

Abstract

Temperature dependences of the static dielectric permittivity and its derivative, obtained for isotropic mesogenic liquids composed of the molecules of different polarity in relation to the basic thermodynamic quantities (internal energy, entropy, and Helmholtz free energy), are analyzed. A role of the molecular polarity in the dielectric behavior of the liquids in the vicinity of the isotropic to nematic phase transition is discussed.

摘要

分析了由不同极性分子组成的各向同性介晶液体相对于基本热力学量(内能、熵和亥姆霍兹自由能)所获得的静态介电常数及其导数的温度依赖性。讨论了分子极性在各向同性向向列相转变附近液体介电行为中的作用。

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