Chen Wei-Zhong, Fanwick Phillip E, Ren Tong
Department of Chemistry, Purdue University, West Lafayette, Indiana 47907, USA.
Inorg Chem. 2007 Apr 30;46(9):3429-31. doi: 10.1021/ic0702623. Epub 2007 Mar 31.
Novel Ru2-containing dendritic compounds were prepared from the CuI-catalyzed 1,3-dipolar cycloaddition between Ru2 compounds containing one or two ethynes, Ru2(D(3,5-Cl2Ph)F)4-n(DMBA-4-C2H)n with n=1 and 2, and azidopoly(benzyl ether) dendrons. These new compounds were also characterized with X-ray diffraction and voltammetric techniques.
新型含钌（II）树枝状化合物是通过含一个或两个乙炔基的钌（II）化合物Ru2(D(3,5-Cl2Ph)F)4-n(DMBA-4-C2H)n（n = 1和2）与叠氮基聚（苄基醚）树枝状分子在碘化亚铜催化下发生1,3 - 偶极环加成反应制备而成。这些新化合物还通过X射线衍射和伏安技术进行了表征。
