钌催化串联交叉复分解/维蒂希烯烃化反应：由末端烯烃生成共轭二烯酸酯
Ruthenium-catalyzed tandem cross-metathesis/Wittig olefination: generation of conjugated dienoic esters from terminal olefins.
作者信息
Murelli Ryan P, Snapper Marc L
机构信息
Merkert Chemistry Center, Boston College, 2609 Beacon Street, Chestnut Hill, Massachusetts 02467-3860, USA.
出版信息
Org Lett. 2007 Apr 26;9(9):1749-52. doi: 10.1021/ol070445t. Epub 2007 Mar 31.
PMID:17397176
Abstract
[reaction: see text] In the presence of ruthenium-based olefin metathesis catalysts and triphenylphosphine, alpha,beta-unsaturated aldehydes can be olefinated with diazoacetates. This ruthenium-catalyzed transformation has been employed in tandem with olefin cross-metathesis to convert terminal olefins into 1,3-dienoic esters in a single operation.
摘要
[反应：见正文] 在钌基烯烃复分解催化剂和三苯基膦存在下，α,β-不饱和醛可与重氮乙酸酯发生烯烃化反应。这种钌催化的转化反应已与烯烃交叉复分解串联使用，可在一步操作中将末端烯烃转化为1,3-二烯酸酯。
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