Murelli Ryan P, Snapper Marc L
Merkert Chemistry Center, Boston College, 2609 Beacon Street, Chestnut Hill, Massachusetts 02467-3860, USA.
Org Lett. 2007 Apr 26;9(9):1749-52. doi: 10.1021/ol070445t. Epub 2007 Mar 31.
[reaction: see text] In the presence of ruthenium-based olefin metathesis catalysts and triphenylphosphine, alpha,beta-unsaturated aldehydes can be olefinated with diazoacetates. This ruthenium-catalyzed transformation has been employed in tandem with olefin cross-metathesis to convert terminal olefins into 1,3-dienoic esters in a single operation.
[反应：见正文] 在钌基烯烃复分解催化剂和三苯基膦存在下，α,β-不饱和醛可与重氮乙酸酯发生烯烃化反应。这种钌催化的转化反应已与烯烃交叉复分解串联使用，可在一步操作中将末端烯烃转化为1,3-二烯酸酯。
