Beckett Michael A, Bland Catherine C, Horton Peter N, Hursthouse Michael B, Varma K Sukumar
School of Chemistry, University of Wales, Bangor, Gwynedd LL57 2UW, UK.
Inorg Chem. 2007 May 14;46(10):3801-3. doi: 10.1021/ic700433e. Epub 2007 Apr 10.
The slow hydrolysis of B(OMe)3 in a CH2Cl2 solution in the presence of 1,8-C10H6(NMe2)2 (5:1 ratio) led to the formation of the novel isolated pentaborate ester anion [B5O6(OMe)4]-, which was characterized by a single-crystal X-ray diffraction study as the salt [1,8-C10H6(NMe2)2H][B5O6(OMe)4].
在1,8 - 二甲基萘(1,8-C10H6(NMe2)2)(比例为5:1)存在的情况下,B(OMe)3在二氯甲烷溶液中缓慢水解,生成了新型的孤立五硼酸酯阴离子[B5O6(OMe)4]-,通过单晶X射线衍射研究将其表征为盐[1,8-C10H6(NMe2)2H][B5O6(OMe)4]。