From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character.

Suppr

超能文献

作者信息

Yao Shenglai, Brym Markus, van Wüllen Christoph, Driess Matthias

机构信息

Technische Universität Berlin, Institute of Chemistry, Metalorganics and Inorganic Materials, Berlin, Germany.

出版信息

Angew Chem Int Ed Engl. 2007;46(22):4159-62. doi: 10.1002/anie.200700398.

DOI:10.1002/anie.200700398

PMID:17436257

Abstract

摘要

相似文献

From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character.

Angew Chem Int Ed Engl. 2007;46(22):4159-62. doi: 10.1002/anie.200700398.

An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination.

J Am Chem Soc. 2010 Nov 17;132(45):15890-2. doi: 10.1021/ja106458p. Epub 2010 Sep 8.

A stable Schrock-type hafnium-silylene complex.

J Am Chem Soc. 2006 Dec 20;128(50):16024-5. doi: 10.1021/ja067251d.

Isolable compounds containing a silicon-silicon double bond.

Science. 1984 Sep 14;225(4667):1109-14. doi: 10.1126/science.225.4667.1109.

Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex.

J Am Chem Soc. 2008 Jul 23;130(29):9226-7. doi: 10.1021/ja803332h. Epub 2008 Jun 27.

Excited-state reactions of an isolable silylene with aromatic compounds.

J Am Chem Soc. 2002 Apr 17;124(15):3830-1. doi: 10.1021/ja025522o.

A stable silicon(0) compound with a Si=Si double bond.

Science. 2008 Aug 22;321(5892):1069-71. doi: 10.1126/science.1160768.

Synthesis and characterization of a coordinated oxoborane: Lewis acid stabilization of a boron-oxygen double bond.

J Am Chem Soc. 2005 Apr 6;127(13):4566-7. doi: 10.1021/ja0507564.

An isolable NHC-supported silanone.

J Am Chem Soc. 2009 Jun 10;131(22):7562-3. doi: 10.1021/ja9031049.

A base-stabilized silylene with a tricoordinate silicon atom as a ligand for a metal complex.

Inorg Chem. 2009 Jun 15;48(12):5058-60. doi: 10.1021/ic900204c.

引用本文的文献

Isolation of a Lewis acid-base stabilized stannanone.

Chem Sci. 2025 Oct 7. doi: 10.1039/d5sc06549f.

Silylene-Stabilized Neutral Dibora-Aromatics with a B═B Bond.

J Am Chem Soc. 2024 Jul 24;146(29):20458-20467. doi: 10.1021/jacs.4c06579. Epub 2024 Jul 9.

En Route to a Molecular Terminal Tin Oxide.

Inorg Chem. 2024 Apr 22;63(16):7455-7463. doi: 10.1021/acs.inorgchem.4c00598. Epub 2024 Apr 10.

Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene.

Chem Sci. 2024 Feb 12;15(11):4161-4170. doi: 10.1039/d3sc06842k. eCollection 2024 Mar 13.

Reactivity of a Strictly T-Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand.

Chemistry. 2023 Jul 11;29(39):e202300818. doi: 10.1002/chem.202300818. Epub 2023 May 23.

Construction of Inorganic Crown Ethers by s-Block-Metal-Templated Si-O Bond Activation.

Angew Chem Int Ed Engl. 2021 Apr 26;60(18):10393-10401. doi: 10.1002/anie.202014822. Epub 2021 Mar 23.

A Stable N-Heterocyclic Silylene with a 1,1'-Ferrocenediyl Backbone.

Angew Chem Int Ed Engl. 2021 Feb 1;60(5):2624-2628. doi: 10.1002/anie.202011691. Epub 2020 Dec 1.

Main Group Multiple Bonds for Bond Activations and Catalysis.

Chemistry. 2021 Jan 26;27(6):1941-1954. doi: 10.1002/chem.202002939. Epub 2020 Nov 19.

Acid-Base Free Main Group Carbonyl Analogues.

Angew Chem Int Ed Engl. 2021 Apr 12;60(16):8626-8648. doi: 10.1002/anie.202008174. Epub 2020 Oct 19.

An Isolable Bis(Silanone-Borane) Adduct.

Chemistry. 2020 Apr 6;26(20):4500-4504. doi: 10.1002/chem.202000235. Epub 2020 Mar 11.

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍。

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

文档翻译

学术文献翻译模型，支持多种主流文档格式。

立即体验

相似文献

From a stable silylene to a mixed-valent disiloxane and an isolable silaformamide-borane complex with considerable silicon-oxygen double-bond character.

Angew Chem Int Ed Engl. 2007;46(22):4159-62. doi: 10.1002/anie.200700398.

An isolable bis-silylene oxide ("disilylenoxane") and its metal coordination.

J Am Chem Soc. 2010 Nov 17;132(45):15890-2. doi: 10.1021/ja106458p. Epub 2010 Sep 8.

A stable Schrock-type hafnium-silylene complex.

J Am Chem Soc. 2006 Dec 20;128(50):16024-5. doi: 10.1021/ja067251d.

Isolable compounds containing a silicon-silicon double bond.

Science. 1984 Sep 14;225(4667):1109-14. doi: 10.1126/science.225.4667.1109.

Alkene hydrosilation by a cationic hydrogen-substituted iridium silylene complex.

J Am Chem Soc. 2008 Jul 23;130(29):9226-7. doi: 10.1021/ja803332h. Epub 2008 Jun 27.

Excited-state reactions of an isolable silylene with aromatic compounds.

J Am Chem Soc. 2002 Apr 17;124(15):3830-1. doi: 10.1021/ja025522o.

A stable silicon(0) compound with a Si=Si double bond.

Science. 2008 Aug 22;321(5892):1069-71. doi: 10.1126/science.1160768.

Synthesis and characterization of a coordinated oxoborane: Lewis acid stabilization of a boron-oxygen double bond.

J Am Chem Soc. 2005 Apr 6;127(13):4566-7. doi: 10.1021/ja0507564.

An isolable NHC-supported silanone.

J Am Chem Soc. 2009 Jun 10;131(22):7562-3. doi: 10.1021/ja9031049.

A base-stabilized silylene with a tricoordinate silicon atom as a ligand for a metal complex.

Inorg Chem. 2009 Jun 15;48(12):5058-60. doi: 10.1021/ic900204c.

引用本文的文献

Isolation of a Lewis acid-base stabilized stannanone.

Chem Sci. 2025 Oct 7. doi: 10.1039/d5sc06549f.

Silylene-Stabilized Neutral Dibora-Aromatics with a B═B Bond.

J Am Chem Soc. 2024 Jul 24;146(29):20458-20467. doi: 10.1021/jacs.4c06579. Epub 2024 Jul 9.

En Route to a Molecular Terminal Tin Oxide.

Inorg Chem. 2024 Apr 22;63(16):7455-7463. doi: 10.1021/acs.inorgchem.4c00598. Epub 2024 Apr 10.

Catalytic hydroboration of aldehydes and ketones with an electron-rich acyclic metallasilylene.

Chem Sci. 2024 Feb 12;15(11):4161-4170. doi: 10.1039/d3sc06842k. eCollection 2024 Mar 13.

Reactivity of a Strictly T-Shaped Phosphine Ligated by an Acridane Derived NNN Pincer Ligand.

Chemistry. 2023 Jul 11;29(39):e202300818. doi: 10.1002/chem.202300818. Epub 2023 May 23.

Construction of Inorganic Crown Ethers by s-Block-Metal-Templated Si-O Bond Activation.

Angew Chem Int Ed Engl. 2021 Apr 26;60(18):10393-10401. doi: 10.1002/anie.202014822. Epub 2021 Mar 23.

A Stable N-Heterocyclic Silylene with a 1,1'-Ferrocenediyl Backbone.

Angew Chem Int Ed Engl. 2021 Feb 1;60(5):2624-2628. doi: 10.1002/anie.202011691. Epub 2020 Dec 1.

Main Group Multiple Bonds for Bond Activations and Catalysis.

Chemistry. 2021 Jan 26;27(6):1941-1954. doi: 10.1002/chem.202002939. Epub 2020 Nov 19.

Acid-Base Free Main Group Carbonyl Analogues.

Angew Chem Int Ed Engl. 2021 Apr 12;60(16):8626-8648. doi: 10.1002/anie.202008174. Epub 2020 Oct 19.

An Isolable Bis(Silanone-Borane) Adduct.

Chemistry. 2020 Apr 6;26(20):4500-4504. doi: 10.1002/chem.202000235. Epub 2020 Mar 11.