来自美味牛肝菌培养液中的新型苯乙二醇。

New phenyl-ethanediols from the culture broth of Boletus edulis.

作者信息

Yang Wan-Qiu, Qin Xiang-Dong, Shao Hong-Jun, Fang Li-Zhen, Wang Fei, Ding Zhi-Hui, Dong Ze-Jun, Liu Ji-Kai

机构信息

State Key Laboratory of Phytochemistry and Plant Resources in West China, Kunming Institute of Botany, Chinese Academy of Sciences, Kunming, P.R. China.

出版信息

J Basic Microbiol. 2007 Apr;47(2):191-3. doi: 10.1002/jobm.200610260.

DOI:10.1002/jobm.200610260

PMID:17440922

Abstract

A new phenyl-ethanediol, (1S)-(4-acetylphenyl)-1, 2-ethanediol (1), and a new natural product, (1S)-(3-ethenylphenyl)-1, 2-ethanediol (2), were isolated from the culture broth of the basidiomycete Boletus edulis together with three related known compounds, 1-(4-ethylphenyl)-1, 2-ethanediol (3), 1-(3-ethylphenyl)-1, 2-ethanediol (4) and 1-(3-formylphenyl)-ethanone (5). Their structures were elucidated by spectroscopic methods including extensive 2D-NMR techniques.

摘要

从担子菌美味牛肝菌的培养液中分离出一种新的苯乙二醇，即(1S)-(4-乙酰基苯基)-1,2-乙二醇(1)，以及一种新的天然产物，(1S)-(3-乙烯基苯基)-1,2-乙二醇(2)，同时还分离出三种相关的已知化合物，1-(4-乙基苯基)-1,2-乙二醇(3)、1-(3-乙基苯基)-1,2-乙二醇(4)和1-(3-甲酰基苯基)-乙酮(5)。通过包括广泛的二维核磁共振技术在内的光谱方法阐明了它们的结构。