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由二聚体结构单元构建的分子钚（IV）化合物的合成与结构表征

Synthesis and structural characterization of a molecular plutonium(IV) compound constructed from dimeric building blocks.

作者信息

Runde Wolfgang, Brodnax Lia F, Goff George S, Peper Shane M, Taw Felicia L, Scott Brian L

机构信息

Chemistry Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USA.

出版信息

Chem Commun (Camb). 2007 May 7(17):1728-9. doi: 10.1039/b617878b. Epub 2007 Feb 6.

DOI:10.1039/b617878b
PMID:17457422
Abstract

Single crystals of Na(8)Pu(2)(O(2))(2)(CO(3))(6) x 12H(2)O, exhibiting bridging mu(2),eta(2)-O(2) ligands in unprecedented Pu(IV) dimeric units, were obtained at ambient temperature from an aqueous Pu(IV) peroxide carbonate solution.

摘要

Na(8)Pu(2)(O(2))(2)(CO(3))(6)·12H(2)O的单晶在室温下由过氧碳酸钚（IV）水溶液制得，该单晶在前所未有的钚（IV）二聚体单元中呈现桥连的μ(2),η(2)-O(2)配体。

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