影响基于降冰片烯的简单电中性阴离子受体识别的空间和电子因素。
Steric and electronic factors influencing recognition by a simple, charge neutral norbornene based anion receptor.
作者信息
Lowe Adam J, Dyson Gail A, Pfeffer Frederick M
机构信息
School of Life and Environmental Sciences, Deakin University, Geelong, VIC, Australia.
出版信息
Org Biomol Chem. 2007 May 7;5(9):1343-6. doi: 10.1039/b703626b. Epub 2007 Mar 22.
DOI:10.1039/b703626b
PMID:17464401
Abstract
Based on (1)H NMR studies, subtle electronic factors rather than pre-organisation dictate the binding stoichiometry of the new, norbornene based, anion hosts 1 and 2 with acetate, however, the binding of dihydrogenphosphate appears to be based solely on steric constraints.
摘要
基于核磁共振氢谱（¹H NMR）研究，新的基于降冰片烯的阴离子主体1和2与乙酸根的结合化学计量比是由微妙的电子因素而非预组织决定的，然而，磷酸二氢根的结合似乎仅基于空间位阻。
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