硝酸铈铵催化的温和及中性脱保护反应。
Mild and neutral deprotections catalyzed by cerium(IV) ammonium nitrate.
作者信息
Maulide Nuno, Vanherck Jean-Christophe, Gautier Arnaud, Markó István E
机构信息
Université catholique de Louvain, Département de Chimie, Bâtiment Lavoisier, Place Louis Pasteur 1, 1348 Louvain-la-Neuve, Belgium.
出版信息
Acc Chem Res. 2007 Jun;40(6):381-92. doi: 10.1021/ar600062b. Epub 2007 May 1.
PMID:17469793
Abstract
The development of a novel, chemoselective, and catalytic deprotection methodology that proceeds under mild and neutral conditions is described, and its mechanism of action is analyzed in some detail. The scope, limitations, and advantages of this protocol are discussed. Selected applications in synthesis are also highlighted.
摘要
本文描述了一种在温和中性条件下进行的新型、化学选择性催化脱保护方法的开发，并对其作用机制进行了详细分析。讨论了该方法的适用范围、局限性和优点。还重点介绍了在合成中的一些选定应用。
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