Template controlled synthesis of a coordinated [11]ane-P2C NHC macrocycle.
作者信息
Kaufhold Oliver, Stasch Andreas, Edwards Peter G, Hahn F Ekkehardt
机构信息
Institut für Anorganische und Analytische Chemie, Universität Münster, Corrensstrasse 36, D-48149, Münster, Germany.
出版信息
Chem Commun (Camb). 2007 May 14(18):1822-4. doi: 10.1039/b617033a. Epub 2007 Feb 8.
DOI:10.1039/b617033a
PMID:17476399
Abstract
Rhenium complex []Cl with the coordinated [11]ane-P(2)C(NHC) macrocycle was obtained by a metal template controlled ring formation reaction; in this reaction a coordinated NH,NH-stabilised imidazolidin-2-ylidene ligand was connected via the nitrogen atoms to two phenyl substituents of a 2-fluorophenyl substituted diphosphine ligand.
摘要
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