聚[[二水合（N，N-二甲基甲酰胺-κO）锰（II）]-μ3-硫酸根]
Poly[[diaqua(N,N-dimethylformamide-kappaO)manganese(II)]-mu3-sulfato].
作者信息
Deng Zhao Peng, Gao Shan, Huo Li Hua, Zhao Hui
机构信息
Laboratory of Functional Materials, School of Chemistry and Materials Science, Heilongjiang University, Harbin 150080, People's Republic of China.
出版信息
Acta Crystallogr C. 2007 May;63(Pt 5):m225-7. doi: 10.1107/S010827010701791X. Epub 2007 Apr 28.
In the title complex, [Mn(SO4)(C(3)H(7)NO)(H2O)2]n, each Mn(II) ion has a distorted octahedral geometry formed by three O atoms of three different sulfate groups, one O atom of a dimethylformamide ligand and two water molecules. The sulfate groups act as tridentate bridging ligands connecting the Mn(II) ions into a two-dimensional layer structure which can be regraded as a 4.8(2) network.
在标题配合物[Mn(SO₄)(C₃H₇NO)(H₂O)₂]ₙ中，每个Mn(II)离子具有由三个不同硫酸根的三个O原子、一个二甲基甲酰胺配体的一个O原子和两个水分子形成的扭曲八面体几何构型。硫酸根作为三齿桥联配体，将Mn(II)离子连接成二维层状结构，该结构可被视为一种4.8(2)网络。
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