Vasconcellos Letícia A, Blando Eduardo, Souto André A, Oliveira Marilia G, Woitchunas Gilséia F P, Hübler Roberto
Gepsi--Centro de Pesquisa e Desenvolvimento Em Física--Tecnopuc, Pontifícia Universidade Católica do Rio Grande do Sul, P.O. Box 1429, 90619-900 Porto Alegre, RS, Brazil.
J Mater Sci Mater Med. 2007 Aug;18(8):1659-63. doi: 10.1007/s10856-007-3034-5. Epub 2007 May 5.
The use of multi-component femoral implants to replace the femur head and re-establish bone motion has been widespread since the 70s. Frequently these implants have spherical metallic heads made of, for example, 316-L stainless steel or Cr-Co alloys, which allow rotational motion towards a polymeric component (UHMWPE). One of the major causes of implant rejection is the generation of UHMWPE debris on the surface between the implant head and the polymeric component. The gamma ray sterilization of implants and the periodical X-ray medical control could contribute to premature degradation of the polymeric surface, resulting in increased wear and shortened lifetime of the implant. In this work we study the degradation degree of the polymeric UHMWPE component as function of the X-ray dose. The elasto-plastic deformation and recovery were carried out by means of a nanohardness tester equipment and the polymer degradation was measured using a fast Fourier transform infra-red (FT-IR) equipment. The results show the compromise among the irradiation doses, the surface oxidation and the mechanical properties of the samples.
自20世纪70年代以来,使用多组件股骨植入物来替换股骨头并重建骨运动已很普遍。这些植入物通常具有由例如316-L不锈钢或铬钴合金制成的球形金属头,其允许朝向聚合物组件(超高分子量聚乙烯,UHMWPE)的旋转运动。植入物排斥的主要原因之一是在植入物头部与聚合物组件之间的表面上产生UHMWPE碎片。植入物的伽马射线灭菌和定期的X射线医学检查可能会导致聚合物表面过早降解,从而导致植入物磨损增加和寿命缩短。在这项工作中,我们研究了作为X射线剂量函数的聚合物UHMWPE组件的降解程度。通过纳米硬度测试仪设备进行弹塑性变形和恢复,并使用快速傅里叶变换红外(FT-IR)设备测量聚合物降解。结果显示了辐照剂量、表面氧化和样品机械性能之间的折衷。