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铅与低成本生物吸附剂——霸王树(仙人掌科多刺仙人掌)的实验性结合

Experimental binding of lead to a low cost on biosorbent: Nopal (Opuntia streptacantha).

作者信息

Miretzky Patricia, Muñoz Carolina, Carrillo-Chávez Alejandro

机构信息

Centro de Geociencias-UNAM, Campus Juriquilla, Juriquilla s/n, 76230 Queretaro, Mexico.

出版信息

Bioresour Technol. 2008 Mar;99(5):1211-7. doi: 10.1016/j.biortech.2007.02.045. Epub 2007 May 9.

Abstract

The use of nopal cladodes (Opuntia streptacantha) as raw material for Pb(2+) biosorption was investigated. Batch experiments were carried out to determine Pb(2+) sorption capacity and the efficiency of the sorption process under different pH, initial Pb(2+) and nopal biomass concentrations. The experimental data showed a good fit to Langmuir and Freundlich isotherms models. The maximum adsorption capacity for Pb(2+) was 0.14 mmol g(-1) with an efficiency higher than 94% (pH 5.0 and 2.5 g L(-1) nopal biomass). The Pb(2+) kinetics were best described by the pseudo-second-order rate model. The rate constant, the initial sorption rate and the equilibrium sorption capacity were determined. The practical implication of this study is the development of an effective and economic technology in which the nopal biomass did not undergo any chemical or physical pretreatment, which added to nopal abundance in Mexico and its low cost makes it a good option for Pb(2+) removal from contaminated waters.

摘要

研究了以仙人掌茎片(Opuntia streptacantha)作为铅离子生物吸附的原材料。进行了批次实验,以确定在不同pH值、初始铅离子浓度和仙人掌生物量浓度下铅离子的吸附容量和吸附过程的效率。实验数据与朗缪尔等温线模型和弗伦德里希等温线模型拟合良好。铅离子的最大吸附容量为0.14 mmol g⁻¹,效率高于94%(pH值为5.0,仙人掌生物量为2.5 g L⁻¹)。铅离子动力学最好用准二级速率模型来描述。测定了速率常数、初始吸附速率和平衡吸附容量。本研究的实际意义在于开发一种有效且经济的技术,其中仙人掌生物量无需进行任何化学或物理预处理,墨西哥仙人掌资源丰富且成本低廉,这使其成为从受污染水体中去除铅离子的良好选择。

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