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中国钱塘江水生生物体内有机氯农药的浓度与特征

Concentrations and characteristics of organochlorine pesticides in aquatic biota from Qiantang River in China.

作者信息

Zhou Rongbing, Zhu Lizhong, Chen Yuyun, Kong Qingxia

机构信息

Department of Environmental Science, Zhejiang University, Hangzhou, Zhejiang 310028, China.

出版信息

Environ Pollut. 2008 Jan;151(1):190-9. doi: 10.1016/j.envpol.2007.02.015. Epub 2007 May 11.

Abstract

The Qiantang River is a typical river flowing through an agricultural area in China. It was studied in 2006 for its aquatic biota quality by determining 13 organochlorine pesticides (OCPs) in the edible parts of crabs, clams, shrimp, fish, aquatic plants, as well as water and sediments collected from seven sites along its upper reaches all the way downstream. The levels of all insecticides were in the range of 17+/-13 (water plants), 35+/-36 (shrimp), 32+/-14 (crabs), 39+/-21 (clams), 47+/-35 (fish) ng/g wet weight (ww) and in the range of 2936+/-2356 (water plants), 5827+/-6013 (shrimp), 2102+/-966 (crabs), 1859+/-1018 (clams), 3624+/-11331 (fish) ng/g lipid. DDT and its metabolites were the predominant contaminants in most biota. A linear relationship was observed between the log bio-concentration factor (BCF) and log octanol-water partition coefficients (Kow) for fish, clams and shrimp. Composition analyses in various environmental media indicated a recent usage of lindane and dicofol into the river.

摘要

钱塘江是一条流经中国农业区的典型河流。2006年,通过测定从钱塘江上游至下游七个地点采集的螃蟹、蛤蜊、虾、鱼、水生植物的可食用部分以及水和沉积物中的13种有机氯农药(OCPs),对其水生生物群质量进行了研究。所有杀虫剂的含量在17±13(水生植物)、35±36(虾)、32±14(螃蟹)、39±21(蛤蜊)、47±35(鱼)纳克/克湿重(ww)范围内,以及在2936±2356(水生植物)、5827±6013(虾)、2102±966(螃蟹)、1859±1018(蛤蜊)、3624±11331(鱼)纳克/克脂质范围内。滴滴涕及其代谢物是大多数生物群中的主要污染物。在鱼类、蛤蜊和虾的对数生物浓缩系数(BCF)和对数正辛醇-水分配系数(Kow)之间观察到线性关系。各种环境介质中的成分分析表明,林丹和三氯杀螨醇近期流入了该河流。

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