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低温玻璃动力学的标准模型描述的是真实的玻璃吗?

Does the standard model of low-temperature glass dynamics describe a real glass?

作者信息

Naumov A V, Vainer Yu G, Kador L

机构信息

Institute of Spectroscopy, Russian Academy of Sciences, Moscow Region, Troitsk 142190, Russia.

出版信息

Phys Rev Lett. 2007 Apr 6;98(14):145501. doi: 10.1103/PhysRevLett.98.145501. Epub 2007 Apr 2.

Abstract

We present the first experimental single-molecule (SM) spectroscopy study of the local dynamics in molecular glasses (frozen toluene and deuterated toluene weakly doped with a substituted terrylene) at T=2-30 K. Surprisingly, the dynamics does not follow the standard model of low-temperature glasses. An extra contribution to the dynamics was detected causing drifts and irreproducible jumps of the SM spectra. The isotope effects in the SM linewidth distribution and the density of states (boson peak) show that the fast dynamics at T=2 K is due to excitations of tunneling nature, whereas at T>7 K it is related to vibrations; H/D atoms are directly involved in both types of excitations.

摘要

我们展示了在T = 2 - 30K温度下对分子玻璃(弱掺杂取代并四苯的冷冻甲苯和氘代甲苯)局部动力学进行的首次实验单分子(SM)光谱研究。令人惊讶的是,该动力学并不遵循低温玻璃的标准模型。检测到对动力学有额外贡献,导致SM光谱出现漂移和不可重复的跳跃。SM线宽分布和态密度(玻色子峰)中的同位素效应表明,T = 2K时的快速动力学归因于隧穿性质的激发,而在T>7K时则与振动有关;H/D原子直接参与了这两种类型的激发。

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