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带有液体电解质的微流控氢燃料电池。

Microfluidic hydrogen fuel cell with a liquid electrolyte.

作者信息

Jayashree Ranga S, Mitchell Michael, Natarajan Dilip, Markoski Larry J, Kenis Paul J A

机构信息

Department of Chemical & Biomolecular Engineering and Beckman Institute for Advanced Science and Technology, University of Illinois at Urbana-Champaign, Urbana, IL 61801, USA.

出版信息

Langmuir. 2007 Jun 19;23(13):6871-4. doi: 10.1021/la063673p. Epub 2007 May 19.

Abstract

We report the design and characterization of a microfluidic hydrogen fuel cell with a flowing sulfuric acid solution instead of a Nafion membrane as the electrolyte. We studied the effect of cell resistance, hydrogen and oxygen flow rates, and electrolyte flow rate on fuel cell performance to obtain a maximum power density of 191 mW/cm2. This flowing electrolyte design avoids water management issues, including cathode flooding and anode dry out. Placing a reference electrode in the outlet stream allows for independent analysis of the polarization losses on the anode and the cathode, thereby creating an elegant catalyst characterization and optimization tool.

摘要

我们报告了一种微流控氢燃料电池的设计与特性,该电池使用流动的硫酸溶液而非纳滤膜作为电解质。我们研究了电池电阻、氢气和氧气流速以及电解质流速对燃料电池性能的影响,以获得191 mW/cm2的最大功率密度。这种流动电解质设计避免了水管理问题,包括阴极水淹和阳极干涸。在流出物流中放置一个参比电极,可以独立分析阳极和阴极上的极化损失,从而创建了一个出色的催化剂表征和优化工具。

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