Lin D F, Lin K L, Chang W C, Luo H L, Cai M Q
Department of Civil and Ecological Engineering, I-Shou University, Dashu Township, Kaohsiung County, Taiwan, ROC.
Waste Manag. 2008;28(6):1081-7. doi: 10.1016/j.wasman.2007.03.023. Epub 2007 May 18.
Sewage sludge ash has been widely applied to cementitious materials. In this study, in order to determine effects of nano-SiO(2) additives on properties of sludge/fly ash mortar, different amounts of nano-SiO(2) were added to sludge/fly ash mortar specimens to investigate their physical properties and micro-structures. A water-binding ratio of 0.7 was assigned to the mix. Substitution amounts of 0%, 10%, 20%, and 30% of sludge/fly ash (1:1 ratio) were proposed. Moreover, 0%, 1%, 2%, and 3% of nano-SiO(2) was added to the mix. Tests, including SEM and compressive strength, were carried out on mortar specimens cured at 3, 7, and 28 days. Results showed that sludge/fly ash can make the crystals of cement hydration product finer. Moreover, crystals increased after nano-SiO(2) was added. Hence, nano-SiO(2) can improve the effects of sludge/fly ash on the hydration of mortar. Further, due to the low pozzolanic reaction active index of sludge ash, early compressive strengths of sludge/fly ash mortar were decreased. Yet, nano-SiO(2) could help produce hydration crystals, which implies that the addition of nano-SiO(2) to mortar can improve the influence of sludge/fly ash on the development of the early strength of the mortar.
污水污泥灰已被广泛应用于胶凝材料。在本研究中,为了确定纳米二氧化硅添加剂对污泥/粉煤灰砂浆性能的影响,向污泥/粉煤灰砂浆试件中添加了不同量的纳米二氧化硅,以研究其物理性能和微观结构。混合料的水灰比设定为0.7。提出了污泥/粉煤灰(1:1比例)替代量为0%、10%、20%和30%的方案。此外,向混合料中添加了0%、1%、2%和3%的纳米二氧化硅。对在3天、7天和28天养护的砂浆试件进行了包括扫描电子显微镜和抗压强度在内的测试。结果表明,污泥/粉煤灰可使水泥水化产物的晶体更细。此外,添加纳米二氧化硅后晶体增多。因此,纳米二氧化硅可改善污泥/粉煤灰对砂浆水化的影响。此外,由于污泥灰的火山灰反应活性指数较低,污泥/粉煤灰砂浆的早期抗压强度有所降低。然而,纳米二氧化硅有助于生成水化晶体,这意味着向砂浆中添加纳米二氧化硅可改善污泥/粉煤灰对砂浆早期强度发展的影响。