首个与卟啉稠合的 N-杂环卡宾配体的合成与结构表征。

Synthesis and structural characterisation of the first N-heterocyclic carbene ligand fused to a porphyrin.

作者信息

Richeter Sébastien, Hadj-Aïssa Aurélie, Taffin Céline, van der Lee Arie, Leclercq Dominique

机构信息

Institut Charles Gerhardt, UM2, CNRS, équipe CMOS, CC 007, Université Montpellier 2, Place Eugène Bataillon, 34095, Montpellier Cedex 05, France.

出版信息

Chem Commun (Camb). 2007 Jun 7(21):2148-50. doi: 10.1039/b704681b. Epub 2007 May 1.

DOI:10.1039/b704681b

PMID:17520118

Abstract

The functionalisation of two neighboring beta-pyrrolic positions of a porphyrin by a fused N-heterocyclic carbene ligand, the subsequent metallation of this external coordination site by palladium(II) and the structural characterisation of the resulting compounds are presented.

摘要

本文介绍了通过稠合的N-杂环卡宾配体对卟啉的两个相邻β-吡咯位置进行功能化，随后用钯（II）对该外部配位位点进行金属化以及对所得化合物的结构表征。